Simultaneous Third order derivative Spectrophotometric Determination of Vanadium and Palladium Using 2-Hydroxy-1-Naphthaldehyde-P-hydroxy Benzoichydrazone (HNHBH)

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Spectrophotometric Determination of Iron(II) and Cobalt(II) by Direct, Derivative, and Simultaneous Methods Using 2-Hydroxy-1-Naphthaldehyde-p-Hydroxybenzoichydrazone

Optimized and validated spectrophotometric methods have been proposed for the determination of iron and cobalt individually and simultaneously. 2-hydroxy-1-naphthaldehyde-p-hydroxybenzoichydrazone (HNAHBH) reacts with iron(II) and cobalt(II) to form reddish-brown and yellow-coloured [Fe(II)-HNAHBH] and [Co(II)-HNAHBH] complexes, respectively. The maximum absorbance of these complexes was found ...

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Ligands of the aroylhydrazone class have shown much promise as potential chelators for treatment of iron overload disease and perhaps cancer (Johnson et al., 1982; Baker et al., 1992; Richardson et al., 1995; Richardson & Milnes, 1997). Our previous investigations have demonstrated that 2-hydroxy-1naphthaldehyde isonicotinoyl hydrazone, (II), and several other aroylhydrazone chelators possess a...

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Direct and Second Order Derivative Spectrophotometric Determination of Vanadium (IV)

A new spectrophotometric method has been developed for the determination of vanadium (IV) in aqueous dimethyl formamide using 2-hydroxy-3-methoxy benzaldehyde thiosemicarbazone (HMBATC) as a chromophoric reagent. The vanadium (IV) reacts with HMBATC forming a dark yellowish green colored water soluble complex, [V(IV)–HMBATSC] in the pH range of 4.0–7.0. The yellowish green colored complex shows...

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Direct Spectrophotometric determination of Aluminum (III) using 5-Bromo-2-hydroxy-3-methoxybenzaldehyde-P- hydroxybenzoic hydrazone

Highly sensitive and selective direct spectrophotometric method is proposed for the determination of aluminium in various real samples. 5-Bromo-2-hydroxy-3-methoxybenzaldehyde-phydroxybenzoic hydrazone reacts with Al(III) forming yellow coloured soluble complex in aqueous dimethyl formamide which has a λmax at 390 nm in the pH range 3.0-7.0. The system obeyed Beer’s law in the range 0.053 – 0.7...

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ژورنال

عنوان ژورنال: IOSR Journal of Applied Physics

سال: 2016

ISSN: 2278-4861

DOI: 10.9790/4861-0804045559